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TO: State Lobbying Group
FROM: Will Drake, State Lobbying Group Member
DATE: February 11, 2008
SUBJECT: Utilizing Coal Combustion Wastes

Intro:
The purpose of this memo is to provide the group with a summary of the research pertaining to the utilization of coal combustion wastes.

The uses of each waste will be summarized in the following order:
  1. Fly Ash
  2. Bottom Ash
  3. Boiler Slag
  4. Flue-Gas Desulfurization Material

Findings:

Fly Ash
80%-90% of the coal combustion waste produced is fly ash. Of this fly ash, 30% is utilized while the rest is landfilled. Fly ash accounts for more than half of all utilized coal waste. Portland cement is the most common and economically beneficial practice. Other applications include:
  • Flowable fill for construction
  • Mining backfill
  • Waste stabilization
  • Manufactured aggregate substitute
  • Snow and ice control
  • Filler for plastic compounds
  • Fuel source
  • Sorbent materials

Bottom Ash
Bottom ash is more porous than fly ash. It can not be added to cement. Because of its high porosity, using bottom ash leads to lighter weight materials. Common Uses are:
  • Structural fills
  • Road base and sub-base pavements
  • Snow and ice control
  • Cinderblock aggregate

Boiler Slag
Almost 90% of the boiler slag utilized is used for roofing grit and blasting granules. Boiler slag is also used in roadway construction. It is mixed into the hot asphalt and improves the life of the road surface.

Flue-Gas Desulfurization (FGD)
FGD material is derived from the “scrubbers” being installed in the smokestacks as a means to make coal burning more environmentally friendly. The scrubber process produces gypsum. This synthetic gypsum has several applications:
  • Wallboard
  • Road base constructing
  • Cement manufacturing
  • Plaster
  • Soil additive
*As more plants are installing scrubbers, the amount of gypsum collected is expected to quickly rise.

Summary

Fly Ash is the most commonly used coal combustion waste. Most fly ash is used in the manufacture of Portland cement. In general, coal combustion waste is used for fill material in the construction of roadways or buildings, or as an aggregate substitute.

Attachments:
See annotated bibliography.





Truini, Joe."Study backs filling mines with coal ash."Waste News.11.24(March 13,
2006):4.General OneFile.Gale.Virginia Tech.6 Feb. 2008
A report from the National Resource Council, titled, “Managing Coal Combustion Residues in Mines,” finds that coal combustion waste, primarily coal ash, can serve as infill for old mines as part of the reclamation process. The report stresses that while this practice is generally safe, more oversight is needed to guard against the potential contamination threat. Steps need to be taken to better identity the composition of the coal ash and the Federal government is called upon to establish mine-filling guidelines.

"Editorial: Coal ash sparks bright ideas."Waste News.7.10(Sept 17, 2001):8.General OneFile.Gale.Virginia Tech.6 Feb. 2008
Article cites generic researchers from Ohio and the Dakotas who are experimenting with the use of fly ash on animal feedlots. The destructive nature of vast congregations of animals, coupled with the limited carrying capacity of the ground, leads to feeds which tend to be muddy and susceptible to massive erosion. The intent is to use the ash to harden and stabilize the soils.

Changwoo, Ann and William Mitsch. “Evaluating the use of recycled coal combustion products in constructed wetlands: an ecologic-economic modeling approach.” Ecological Modelling. 150. (2002) 117-140.
Scientists from Ohio State Universty have conducted experiments showing the benefits of using flue-gas desulfurization, a coal combustion waste, for liner material in constructed wetlands for such applications as municipal water treatment. The researchers constructed scale model wetlands and measured the results. Simulations showed increases in phosphorous retention by amounts of 10%, which translates into substantial cost savings.

"Coal ash promotes plant growth."Israel Business Today.6.n257(Dec 27,
1991):5(1).General OneFile.Gale.Virginia Tech.6 Feb. 2008
<http://find.galegroup.com.ezproxy.lib.vt.edu:8080/itx/infomark.do?&contentSet=I
ACDocuments&type=retrieve&tabID=T003&prodId=ITOF&docId=A11861043&source=gale&srcprod=ITOF&userGroupName=viva_vpi&version=1.0>.
The Hebrew University’s agriculture department has found coal ash can be added to the soil for use as a growth additive. When properly mixed with cow manure, the ash becomes a fertile soil base for plants. The findings claim 20%-30% faster growth rates. Professor Yone Chen has hopes of this method being beneficial in areas of nutrient-poor or depleted soils.

United States. Department of Energy, Office of Fossil Energy. Coal Utilization By-
Products. Topical Report Number 24. August 2006.
<http://www.netl.doe.gov/technologies/coalpower/cctc/topicalreports/pdfs/Topical2
4.pdf>
This report was commissioned by the Department of Energy and was put together by the National Energy Technology Laboratory. It provides a detailed breakdown of the major components of coal combustion waste and the specific utilization of the by-products of each group. The report highlights uses for fly ash, bottom ash, flue-gas desulfurization, and boiler slag. The report does not ignore the potential risks of using coal waste, but it mainly glosses over such concerns. It comes to the conclusion that utilization of coal waste is both an economically and environmentally beneficial.


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rjohns04 Giles County Partnership For Excellence: Fly Ash Information 0 Feb 10 2008, 5:17 PM EST by rjohns04
Thread started: Feb 10 2008, 5:17 PM EST  Watch
This is our opposition’s website. There is some pretty good information on the basics of coal ash, as well as what exactly is going to be used as "structural fill". There are various references made throughout the page, most notably to previously published EPA reports and a U.S. Geological Survey.

Unknown. (2007). Talking Points; Giles County Partnership for Excellence Foundation’s
Cumberland Park Structural CCB Fill. The Giles County Partnership for Excellence Foundation. Received on February 8, 2008 from
http://gilespartnership.org/fly-ash-info.html
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wmarley Other coal combustion byproducts: sludge. 0 Feb 6 2008, 3:12 PM EST by wmarley
Thread started: Feb 6 2008, 3:12 PM EST  Watch
Apparantly there are many different wastes resulting from coal combustion as well as many different names for them, which this website helps describe a little

http://industrialwastewatcher.wordpress.com/2007/08/02/coal-combustion-waste-by-any-other-name-is-still-waste/

but I wanted to focus on FGD sludge and see the effects of that waste of coal combustion. This website summarizes it:

http://www.tfhrc.gov/hnr20/recycle/waste/fgd1.htm

To reduce SO2 emissions, coal plants implement a wet scrubber system called a flue gas desulfurization system. The result is an off-white slurry that has flue gas incorporated into it. This stuff can’t be deposited in land, so there are many options for cleaning or detoxing this substance including: dewatering, and oxidizing. These are explained in the website.
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mscott22 Website to Check Out 0 Feb 3 2008, 2:43 PM EST by mscott22
Thread started: Feb 3 2008, 2:43 PM EST  Watch
This website came up as I searched for information. It is the website of an organization promoting the reuse of CCPs. Check it out, its kind of interesting and may provide some of the basic information/templates for our information: http://www.wrashg.org/org.htm

And I quote from their website:
"The Western Region Ash Group is an informal association of producers, users, regulators, researchers and others interested in coal combustion products (CCPs). These materials include fly ash, bottom ash and flue gas desulfurization residues. Members are involved in reuse of CCPs including researching new applications or making others aware of the many uses of these versatile products."
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